Which number president was John Quincy Adams?

Who served as Vice President under James Monroe? Under which president did Daniel D. Tompkins serve as Vice President? Who was First Lady during James Monroe's presidency? Elizabeth Monroe was married to which president? Who succeeded John Quincy Adams as President of the United States? Who was President immediately before John Quincy Adams? Which president served from 1825 to 1829? In what year did John Quincy Adams first take office as President?